Microbially-charged electrochemical fuel for energy storage in a redox flow cell

Santos, Márcia S. S.; Peixoto, Luciana; Azevedo, João; Monteiro, Ricardo A. R.; Ferreira, Célia; Alves, M. Madalena; Mendes, Adélio

http://hdl.handle.net/10400.2/11804

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Authors

Santos, Márcia S. S.

Peixoto, Luciana

Azevedo, João

Monteiro, Ricardo A. R.

Ferreira, Célia

Alves, M. Madalena

Mendes, Adélio

Abstract(s)

A Bioelectrochemical System (BES) is used for charging an electrochemical fuel to be used in a Redox Flow Cell (RFC), demonstrating the first proof of concept of a microbially-charged electrochemical fuel. Geobacter sulfurreducens, electroactive bacteria, was used to charge anthraquinone-2,6-disulfonate (2,6-AQDS) producing current densities of ca. 200–500 mA m 2 and maximum power densities of ca. 33 mW m 2 . The microbially-charged electrochemical fuel and potassium ferricyanide, K3[Fe(CN)6] were introduced in a RFC producing a potential difference of 0.62 V, with a ca. 80% energy conversion efficiency. The use of a BES for charging the posilyte of a RFC is now envisioned. The bio-conversion of waste biomass energy into electrochemical fuels (microbiallycharged electrochemical fuel for negalyte and posilyte) for later use in a RFC to produce electricity is a promising approach of converting biomass into storable and easy to use energy.