Repository logo
 
Publication

Polypyrrole-TiO2 composite for removal of 4-chlorophenol and diclofenac

2020-01Journal article Restricted access
Simple item page
dc.contributor.authorSilvestri, Siara
dc.contributor.authorBurgo, Thiago Augusto Lima
dc.contributor.authorFerreira, Célia
dc.contributor.authorLabrincha, João
dc.contributor.authorTobaldi, David
dc.date.accessioned2022-03-04T12:45:11Z
dc.date.available2022-03-04T12:45:11Z
dc.date.issued2020-01
dc.date.updated2022-01-15T15:57:44Z
dc.description.abstractIn this work, we successfully synthesized TiO2-polypyrrole (PPy) composite material via polymerization method using the sulfuric acid (H2SO4) as an oxidizing agent. Different characterization techniques, including electrostatic force microscopy, confirmed that TiO2 was intimately attached on PPy. The photocatalytic activity of PPyTiO2 composite was studied experimentally for the conversion of diclofenac (DCF)– one of the most frequently detected pharmaceutical compounds in the aquatic environment – and 4-chlorophenol (4-CP) - largely used in the bleaching of cellulose pulp in the paper industry, as herbicide and pesticide - under simulated solar light irradiation at environmental conditions. This is the first time that a composite PPy-TiO2 was used as photocatalyst for the conversion of 4-CP. Results showed that the PPy-TiO2 was able to convert more than 90% of DCF and 40% of 4-CP in just 60 min, showing stability and efficiency over five consecutive cycles of reuse for both pollutants. The produced PPy-TiO2 showed higher photocatalytic efficiency compared to that of TiO2, thus proving itself to be a promising photocatalyst.pt_PT
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.doi10.1016/j.reactfunctpolym.2019.104401pt_PT
dc.identifier.issn1381-5148
dc.identifier.slugcv-prod-1819483
dc.identifier.urihttp://hdl.handle.net/10400.2/11802
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.subjectPPy-TiO2pt_PT
dc.subject4-chlorophenolpt_PT
dc.subjectDiclofenacpt_PT
dc.subjectPhotocatalysispt_PT
dc.titlePolypyrrole-TiO2 composite for removal of 4-chlorophenol and diclofenacpt_PT
dc.typejournal article
dspace.entity.typePublication
oaire.citation.startPage104401pt_PT
oaire.citation.titleReactive and Functional Polymerspt_PT
oaire.citation.volume146pt_PT
person.familyNameSilvestri
person.familyNameBurgo
person.familyNameFerreira
person.familyNameLabrincha Baptista
person.familyNameTobaldi
person.givenNameSiara
person.givenNameThiago Augusto Lima
person.givenNameCélia
person.givenNameJoão António
person.givenNameDavid Maria
person.identifier1518999
person.identifierB-3984-2010
person.identifier.ciencia-id931E-FBDE-2098
person.identifier.ciencia-idD819-2C2C-7A16
person.identifier.ciencia-id6515-3493-6B27
person.identifier.orcid0000-0003-2666-6102
person.identifier.orcid0000-0003-2521-3574
person.identifier.orcid0000-0002-7456-2538
person.identifier.orcid0000-0003-4782-1685
person.identifier.orcid0000-0002-0112-8570
person.identifier.ridG-2080-2012
person.identifier.scopus-author-id42862633900
person.identifier.scopus-author-id23984376200
person.identifier.scopus-author-id7003372169
rcaap.cv.cienciaid931E-FBDE-2098 | Célia Maria Dias Ferreira
rcaap.rightsrestrictedAccesspt_PT
rcaap.typearticlept_PT
relation.isAuthorOfPublication46ebf644-04eb-456d-98e0-b57c89c9dbfa
relation.isAuthorOfPublication2e31436a-716e-4ff6-9374-2a7993af2ed1
relation.isAuthorOfPublicatione30010dd-0512-4da6-a0c9-910b47f18b4f
relation.isAuthorOfPublicationeec23928-f900-47ca-8d28-fc13d814779c
relation.isAuthorOfPublication129bbaa2-c7f3-477c-8317-f3672997a44b
relation.isAuthorOfPublication.latestForDiscoverye30010dd-0512-4da6-a0c9-910b47f18b4f

Files

Original bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
2020-Siara_et_al-Polypyrrole_PUBLISHED.pdf
Size:
3.51 MB
Format:
Adobe Portable Document Format
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.97 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

Ambiente e Sustentabilidade | Artigos em revistas internacionais / Papers in international journals