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In pursuit of a high-temperature, high-pressure, high-viscosity standard: the case of Tris(2-ethylhexyl) Trimellitate

2017-09Journal article Restricted access
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dc.contributor.authorWakeham, William A.
dc.contributor.authorAssael, Marc J.
dc.contributor.authorAvelino, Helena Maria da Nóbrega Teixeira
dc.contributor.authorBair, Scott
dc.contributor.authorBaled, Hseen O.
dc.contributor.authorBamgbade, Babatunde A.
dc.contributor.authorBazile, Jean-Patrick
dc.contributor.authorCaetano, Fernando J. P.
dc.contributor.authorComunas, Maria J. P.
dc.contributor.authorDaridon, Jean-Luc
dc.contributor.authorDiogo, João C. F.
dc.contributor.authorEnick, Robert M.
dc.contributor.authorFareleira, João M. N. A.
dc.contributor.authorFernandez, Josefa
dc.contributor.authorOliveria, M. Conceicao
dc.contributor.authorSantos, Tânia V. M.
dc.contributor.authorTsolakidou, Chrysi M.
dc.date.accessioned2017-12-29T14:09:57Z
dc.date.available2017-12-29T14:09:57Z
dc.date.issued2017-09
dc.description.abstractThis paper presents a reference correlation for the-viscosity of tris(2-ethylhexyl) trimellitate designed to serve in industrial applications for the calibration of viscometers at elevated temperatures and pressures such as those encountered in the exploration of oil reservoirs and in lubrication. Tris(2-ethylhexyl) trimellitate has been examined with respect to the criteria necessary for an industrial standard reference material such as toxicity, thermal stability, and variability among manufactured lots. The viscosity correlation has been based upon all of the data collected in a multinational project and is supported by careful measurements and analysis of all the supporting thermophysical property data that are needed to apply the standard for calibration to a wide variety of viscometers. The standard reference viscosity data cover temperatures from 303 to 473 K, pressures from 0.1 to 200 MPa, and viscosities from approximately 1.6 to 755 mPa s. The uncertainty in the data provided is of the order of 3.2% at 95% confidence level, which is thought to be adequate for most industrial applications.pt_PT
dc.description.sponsorshipThis work has been conducted under the guidance of the International Association for Transport Properties (IATP; http://transp.cheng.auth.gr/index.php/iatp/terms). The work described in this paper was carried out under the auspices of the International Union of Pure and Applied Chemistry (IUPAC) within the framework of the Project 2012-051-1-100. This work was supported by the strategic project PEst-OE/QUI/UI0100/ 2013 funded by Fundação para a Ciência e a Tecnologia (FCT), ̂Portugal. The authors are grateful to Ana Dias research technician fellowship at the Node IST at CQE of the Portuguese Mass Spectrometry Network, project REM2013 funded by Fundação para a Ciência e a Tecnologia (FCT), Portugal. ̂M.J.P.C. and J.F. acknowledge the support of the Spanish Ministry of Economy and Competitiveness and the FEDER program through the ENE2014-55489-C2-1-R project as well as of Xunta de Galicia through the EM2013/031 and GRC ED431C 2016/001 Projects. J.F. and M.J.P.C. acknowledge the assistance of J. M. Liñeira del Rio and M. J. G. Guimarey for the viscosity measurements.pt_PT
dc.description.sponsorshipFundação para a Ciência e a Tecnologia (FCT), Portugal E/QUI/UI0100/2013
dc.description.sponsorshipThe work described in this paper was carried out under the auspices of the International Union of Pure and Applied Chemistry (IUPAC) within the framework of the Project 2012-051-1-100. This work was supported by the strategic project PEst-OE/QUI/UI0100/ 2013 funded by Fundaca̧ o para a Cie ̃ ncia e a Tecnologia (FCT), ̂ Portugal. The authors are grateful to Ana Dias research tech nician fellowship at the Node IST at CQE of the Portuguese Mass Spectrometry Network, project REM2013 funded by Fundaca̧ o para a Cie ̃ ncia e a Tecnologia (FCT), Portugal. ̂ M.J.P.C. and J.F. acknowledge the support of the Spanish Ministry of Economy and Competitiveness and the FEDER program through the ENE2014-55489-C2-1-R project as well as of Xunta de Galicia through the EM2013/031 and GRC ED431C 2016/001 Projects. J.F. and M.J.P.C. acknowledge the assistance of J. M. Liñ eira del Rio and M. J. G. Guimarey for the ́ viscosity measurements
dc.description.versioninfo:eu-repo/semantics/publishedVersionpt_PT
dc.identifier.doi10.1021/acs.jced.7b00170pt_PT
dc.identifier.issn0021-9568
dc.identifier.urihttp://hdl.handle.net/10400.2/6869
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.publisherAmerican Chemical Societypt_PT
dc.subjectSurface-tension measurementspt_PT
dc.subjectIndustrial reference fluidpt_PT
dc.subjectPotential reference fluidpt_PT
dc.subjectTransport-coefficientspt_PT
dc.subjectDensity-measurementspt_PT
dc.titleIn pursuit of a high-temperature, high-pressure, high-viscosity standard: the case of Tris(2-ethylhexyl) Trimellitatept_PT
dc.typejournal article
dspace.entity.typePublication
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/3599-PPCDT/PEst-OE%2FQUI%2FUI0100%2F2013/PT
oaire.citation.endPage2895pt_PT
oaire.citation.issue9pt_PT
oaire.citation.startPage2884pt_PT
oaire.citation.titleJournal of Chemical and Engineering Datapt_PT
oaire.citation.volume62pt_PT
oaire.fundingStream3599-PPCDT
person.familyNameAvelino
person.familyNameCaetano
person.familyNameFareleira
person.givenNameHelena Maria da Nóbrega Teixeira
person.givenNameFernando J. P.
person.givenNameJoão
person.identifier.ciencia-id9615-6337-5695
person.identifier.ciencia-idDE17-708E-317F
person.identifier.ciencia-id8E1B-F54C-8ABD
person.identifier.orcid0000-0001-6516-2164
person.identifier.orcid0000-0002-6821-1694
person.identifier.orcid0000-0002-8442-9386
person.identifier.ridH-8325-2012
person.identifier.scopus-author-id14919229800
person.identifier.scopus-author-id7004474824
person.identifier.scopus-author-id6603840268
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsrestrictedAccesspt_PT
rcaap.typearticlept_PT
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